Liquid chromatographic separation of carboxylic acids with the H-form cation-exchange resin
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چکیده
منابع مشابه
Carboxylic cation exchange resin effects in dogs.
Reports describing trials of exchange resins in removing cations from the gastrointestinal tract of experimental animals have been limited to toxicity studies and to measurements of the relative magnitudes of the oral intake and the stool output (1-3). In the experiments presented in this paper changes in serum, urine, and stool components, as well as the external and internal balances of certa...
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In this study, a cation-exchange resin (CEX) of the K(+)-form, i.e., an enhancer resin, is used as a postcolumn conductimetric enhancer in the ion-exclusion chromatography of aliphatic carboxylic acids. The enhancer resin is filled in the switching valve of an ion chromatograph; this valve is usually used as a suppressor valve in ion-exchange chromatography. An aliphatic carboxylic acid (e.g., ...
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Zinc isotope separations were studied by displacement chromatography using the chelating properties of malate, citrate and lactate exchange resin and EDTA as ligands. After each chromatographic operation, the heavier zinc isotopes were found to preferentially fractionated into the carboxylate complex solution phase. The separation coefficients (epsilon) for zinc isotope separation had the large...
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Estimation of plasma catecholamine concentrations by "high-performance" liquid chromatography, although increasingly used, still presents difficulties. We describe a method for clean-up of plasma samples on cation-exchange resin before they are extracted with alumina. This procedure eliminates many of the interfering compounds often present in plasma extracts prepared with the alumina treatment...
متن کاملModeling of Ion-exclusion and Vacancy Ion-exclusion Chromatography on a Strongly Acidic Cation-exchange Resin in the H+ Form
Ion-exclusion chromatography (IEC) can sometimes be used for separation of the weak acids using pure water as mobile phase. Characteristic leading (i.e. frontally tailing) peaks are obtained and retention depends on the concentration of solutes. It was recently shown that this order could be reversed. In vacant ion exclusion chromatography (vIEC) sample flows as mobile phase and pure water is i...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1974
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.23.12_1522